Mechanistic studies on oxidation of hydrazine by a µ-oxo diiron(iii,iii) complex in aqueous acidic media—proton coupled electron transfer
✍ Scribed by Bhattacharyya, Jhimli; Dutta, Kabita; Mukhopadhyay, Subrata
- Book ID
- 120341495
- Publisher
- Royal Society of Chemistry
- Year
- 2004
- Tongue
- English
- Weight
- 391 KB
- Volume
- 18
- Category
- Article
- ISSN
- 1477-9226
- DOI
- 10.1039/B407980A
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📜 SIMILAR VOLUMES
## Abstract Examined in this study is the kinetics of a net 2e^−^ transfer between [Fe~2~(__μ__‐O)(phen)~4~(H~2~O)~2~]^4+^ (1) and its hydrolytic derivatives [Fe~2~(__μ__‐O)(phen)~4~(H~2~O)(OH)]^3+^ (2) and [Fe~2~(__μ__‐O)(phen)~4~(OH)~2~]^2+^ (3) with $\rm{{{NO}}\_{{2}}^ - }$ in aqueous media and
Manganese(III) solutions were prepared by known electrochemical methods in sulfuric acid, acetic acid, and pyrophosphate media. The nature of the oxidizing species present in manganese(III) solutions was characterized by spectrophotometric and redox potential measurements. Kinetics of oxidation of L