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One- and Two-Dimensional Solid-State 13 C NMR Analyses of the Solid Structure and Molecular Motion of Poly(ε-caprolactone) Isothermally Crystallized from the Melt

✍ Scribed by Kaji, Hironori; Horii, Fumitaka


Book ID
127271737
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
341 KB
Volume
30
Category
Article
ISSN
0024-9297

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Solid-state 13C NMR analyses of the stru
✍ Hideto Tsuji; Sachie Kamo; Fumitaka Horii 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 486 KB

The effects of crystallinity, water absorption, hydrolytic degradation, and tacticity on the solid structure and chain mobility of poly(lactide)s were investigated by solid-state 13 C NMR spectroscopy. The following results were obtained from the line shapes of the carbonyl and methine carbons in 13