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One- and Two-Dimensional Refocused INADEQUATE NMR Experiments

✍ Scribed by T. Nakai; C.A. Mcdowell

Publisher: Elsevier Science
Year: 1993
Tongue: English
Weight: 498 KB
Volume: 104
Category: Article
ISSN: 1064-1858
DOI: 10.1006/jmra.1993.1202

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✦ Synopsis

We describe details of the refocused INADEQUATE method, which yields in-phase (J) doublets from ({ }^{13} \mathrm{C}-{ }^{13} \mathrm{C}) spin pairs in natural-abundance samples. The procedure for obtaining twodimensional pure-absorptive INADEQUATE spectra is explained. This is used to determine (J) coupling constants with high accuracy because of higher spectral resolution than that obtained in magnitude-mode spectra. The method has been demonstrated using hexanoic acid and hexadecanoic acid as test samples. 1993 Academic Press, Inc.

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