On the validity of the polarographic determination of stability constants of metal ions in the case of adsorbable electroactive species
β Scribed by M. Sluyters-Rehbach; J.H. Sluyters
- Publisher
- Elsevier Science
- Year
- 1972
- Weight
- 272 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0022-0728
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π SIMILAR VOLUMES
The polarographlc/voltammetnc deternunatlon of complexatlon constants, Influenced by hgand-Induced adsorption of metal ions, was studled The factors affecting the final results, such as the "speed" of the applied technique, metal concentration, lomc strength and data treatment were examined, takmg l
A general method for determination of the stability constants of complexes of crown ethers and related compounds with small organic molecules in polar solvents is described, based on an indirect polarographic procedure. Computerized evaluation of the data forms an essential part of the procedure.