Influence of anion-induced adsorption on the polarographic/voltammetric determination of stability constants
✍ Scribed by Marina Zelić; Marko Branica
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 831 KB
- Volume
- 268
- Category
- Article
- ISSN
- 0003-2670
No coin nor oath required. For personal study only.
✦ Synopsis
The polarographlc/voltammetnc deternunatlon of complexatlon constants, Influenced by hgand-Induced adsorption of metal ions, was studled The factors affecting the final results, such as the "speed" of the applied technique, metal concentration, lomc strength and data treatment were examined, takmg lead(II) and cadmrum(II) m halide solutions as model systems A comparison was made of the observations wtth exlstmg theoretical predictions
📜 SIMILAR VOLUMES
The equations for the influence of non-equilibrated, linear adsorption of a reactant, an intermediate and a product of the reversible redox reaction at stationary, planar electrode, under potentiostatic regime, have been derived.