On the validity of marcus relationship for dissociative electron transfer reactions in solution
✍ Scribed by Victor Pérez; José M. Lluch; Juan Bertrán
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 860 KB
- Volume
- 60
- Category
- Article
- ISSN
- 0167-7322
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Some recent studies of inner-sphere and outer-sphere electron-transfer reactions in solution are described. Various indirect criteria for determining the mechanisms of electron-transfer re actions and the question of ligand bridging at electrodes are discussed.
## Abstract Electron transfer in the cations of bis(hydrazines), bridged by six different π‐systems (compounds 1–6) is studied using __ab initio__ and density functional theory (DFT) methods. Due to ionization from an antibonding combination of the lone‐pair orbitals of the nitrogens in one of the