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Observation of temperature independent heterogeneous electron transfer reactions in the inverted Marcus region

✍ Scribed by Jacques E. Moser; Michael Grätzel

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
838 KB
Volume
176
Category
Article
ISSN
0301-0104

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Construction of SnIV Porphyrin/Trinuclea
Construction of SnIV Porphyrin/Trinuclear Ruthenium Cluster Dyads Linked by Pyridine Carboxylates: Photoinduced Electron Transfer in the Marcus Inverted Region
✍ Takahiko Kojima; Kakeru Hanabusa; Kei Ohkubo; Motoo Shiro; Shunichi Fukuzumi 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 416 KB 👁 2 views

## Abstract Novel conglomerates consisting of saddle‐distorted Sn^IV^(DPP) (H~2~DPP=dodecaphenylporphyrin) complexes and μ~3~‐O‐centered and carboxylato‐bridged trinuclear Ru^III^ clusters linked by pyridine carboxylates were synthesized and characterized. Sn^IV^–DPP complexes with Cl^−^, OH^−^, an