On the use of the Bayliss-McRae dispersion model in NMR solvent effects
β Scribed by Frans H.A. Rummens
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 383 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0009-2614
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π SIMILAR VOLUMES
## Abstract The NMR spectra of pyridine, pyrazine and imidazole are examined in acetoneβ__d__~6~. The differential shifts of the ring protons are accounted for in terms of an interaction between the lone pair on the ring nitrogen atom and the carbonyl group of acetone.
A recently developed method to calculate singlet and triplet gauge-originαindependent magnetic properties of solvated molecules is applied to the study of those parameters that determine an observed nuclear magnetic resonance signal: the magnetizability, the nuclear shieldings, and the indirect spin