Theoretical predictions for the spin-echo amplitude attenuation in a field-gradient NMR experiment in a porous medium are presented for both continuous and pulsed spectroscopy. The diffusion is modelled by a random walk process on a fractal network and should correspond to observations in well-chara
✦ LIBER ✦
On the use of NMR pulsed field-gradient spectroscopy for the study of anomalous diffusion in fractal networks
✍ Scribed by Jörg Kärger; Günter Vojta
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 237 KB
- Volume
- 141
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Theoretical questions of NMR spin echo attenuation due to diffusion in fractal systems are examined. The mean-square displacement of anomalous diffusion depends sublinearly on time. Therefore, this stochastic process is not invariant against time translation. The correct adjustment of the time scale is a crucial prerequisite for the proper reflection of molecular migration by means of spin-echo experiments.
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