Rate coefficients have been measured for the reaction of OH radicals with methylglyoxal from 260 to 333 K using the discharge flow technique and laser-induced fluorescence detection of OH. The rate coefficient was found to be (1.32 IT 0.30) X cm3 molecule-' s-l at room temperature, with a distinct n
On the Uncertainties in the Rate Coefficients for OH Reactions with Hydrocarbons, and the Rate Coefficients of the 1,3,5-Trimethylbenzene and m -Xylene Reactions with OH Radicals in the Gas Phase
β Scribed by Kramp, Franz; Paulson, Suzanne E.
- Book ID
- 126249991
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 72 KB
- Volume
- 102
- Category
- Article
- ISSN
- 1089-5639
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract The relativeβrate method has been used to determine the rate coefficients for the reactions of OH radicals with three C~5~ biogenic alcohols, 2βmethylβ3βbutenβ2βol (__k__~1~), 3βmethylβ3βbutenβ1βol (__k__~2~), and 3βmethylβ2βbutenβ1βol (__k__~3~), in the gas phase. OH radicals were prod
3-Methylfuran has been identified as a product of the gas-phase reaction of the OH radical with isoprene, and under simulated atmospheric conditions a formation yield of 0.044 -t 0.006 was determined. In an analogous manner, the OH radical reaction with 1,3-butadiene formed furan with a yield of 0.0
## Abstract Using a relative kinetic technique, rate coefficients have been determined at (298 Β± 2) K and atmospheric pressure for the gasβphase reactions of the NO~3~ radical with three vicinal dihydroxy aromatic compounds. The experiments were carried out in a 1080βl quartz glass reactor at the B