✦ LIBER ✦

On the Trimerization of Cyanoacetylene: Mechanism of Formation of Tricyanobenzene Isomers and Laboratory Detection of Their Radio Spectra

✍ Scribed by Prof. Dr. Henning Hopf; Cornelia Mlynek; Prof. Dr. Robert J. McMahon; Jessica L. Menke; Prof. Dr. Alberto Lesarri; Dr. Michael Rosemeyer; Prof. Dr. Jens-Uwe Grabow

Publisher: John Wiley and Sons
Year: 2010
Tongue: English
Weight: 370 KB
Volume: 16
Category: Article
ISSN: 0947-6539
DOI: 10.1002/chem.201001648

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

In support of a deeper understanding of the chemistry of cyanoacetylene—a known constituent of planetary atmospheres and interstellar space—theoretical and experimental studies address the chemical mechanism of dimerization and trimerization, and provide high‐resolution rotational spectra of two of the trimeric products, 1,2,3‐ and 1,2,4‐tricyanobenzene. Analysis of the rotational spectra is particularly challenging because of quadrupolar coupling from three ^14^N nuclei. The laboratory rotational spectra provide the basis for future searches for these polar aromatic compounds in interstellar space by radio astronomy.

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