On the time response of the itinerant oscillator model of polar fluids
โ Scribed by W.T. Coffey; J.G. Pearce; J.H. Calderwood
- Publisher
- Elsevier Science
- Year
- 1981
- Weight
- 565 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0378-4487
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๐ SIMILAR VOLUMES
Analysis of the itinerant oscillator model of polar fluids has hitherto been concentrated on the small-oscillation approximation. This has neglected one important contribution to the dynamic polarization, namely relaxation due to crossing of dipoles over the hills of the cosine potential for dipole-
The problem of including both inertial and non-linear effects in the dielectric rehxsation of an assembly of molecules containing rotating polar groups is treated analytically\_ Approximate solutions for the dipole autocorrelation function and the comples polartiability sugest that the related relax