On the thermal reorganization of 6-carboethoxybicyclo [3.1.0] hex-2-ene
โ Scribed by Robert A. Clark
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- French
- Weight
- 196 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0040-4039
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irradiation of 1 in methanol with h 254 nm yields J, and 4 as the main primary products whiFh result from the excited singlet state by initial cyclopropane bond homolysis, but no primary photosolvolysis products.
AS an extension of our studies on the photochemical Diels-Alder reaction of 1,3,5-hexatrienes to bicyclo[3.l.O]hex-2-enes, 1 we became interested in determining the stereochemical consequences attending the thermal cycloreversion of the bicyclo[3.l.O]hex-2-ene system. The parent carbocycle is known
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