On the Thermal Decomposition of Methyl Nitrite
β Scribed by A. G. Carter and Morris W. Travers
- Book ID
- 123674308
- Publisher
- The Royal Society
- Year
- 1937
- Tongue
- English
- Weight
- 611 KB
- Volume
- 158
- Category
- Article
- ISSN
- 0962-8444
- DOI
- 10.2307/96891
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## Abstract The effects of NO on the decomposition of CH~3~ONO have been investigated in the temperature range 450β520 K at a constant pressure of 710 torr using He as buffer gas. The measured timeβdependent concentration profiles of CH~3~ONO, NO, N~2~O, and CH~2~O can be quantitatively accounted f
The unimolecular decomposition of methyl nitrite in the temperature range 680-955 K and pressure range 0.64 to 2.0 atm has been studied in shock-tube experiments employing real-time absorption of CW CO laser radiation by the NO product. Computer kinetic modeling using a set of 23 reactions shows tha