## Abstract The cyclic sulfenic ester 1,2‐oxathiolane (**1**) decomposes thermally (400 – 450 K) exclusively to give acrolein (**3**) __via__ 3‐mercaptopropanal (**2**) by loss of hydrogen sulfide. Isotopic labelling experiments reveal the presence of a 1,2‐oxathiolane‐thietane 1‐oxide equilibrium
On the Thermal Cycloisomerization of Long-Chain Alkylacetylenes in the Gas Phase
✍ Scribed by Ondruschka, Bernd ;Zimmermann, Gerhard ;Remmler, Matthias ;Ziegler, Ulrich ;Kopinke, Frank-Dieter ;Olk, Bernhard ;Findeisen, Matthias
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1989
- Tongue
- English
- Weight
- 535 KB
- Volume
- 122
- Category
- Article
- ISSN
- 0009-2940
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