𝔖 Bobbio Scriptorium
✦   LIBER   ✦

On the theory of adiabatic electron-tranfers reactions in polar solvents

✍ Scribed by A.B. Helman


Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
657 KB
Volume
79
Category
Article
ISSN
0301-0104

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Energetics of electron transfer reaction
✍ M. Tachiya πŸ“‚ Article πŸ“… 1994 πŸ› Elsevier Science 🌐 English βš– 313 KB

The free energy change of an electron transfer reaction in a polar solvent is rigorously analyzed within the framework of the dielectric continuum model. An appropriate expression for the electrostatic energy between the two product ions separated by R is derived. The present result does not support

Effect of the dielectric saturation on t
✍ M. Tachiya πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 English βš– 463 KB

Recently Kakitani and Mataga claimed that the free energy dependence of electron transfer rates in polar solvents could be explained by taking into account the dielectric saturation effect of polar solvents. It is shown that the basic assumption of their model is incorrect. The correct treatment of

On the theory of long-range electron hop
✍ A. M. Kuznetsov; J. Ulstrup πŸ“‚ Article πŸ“… 1982 πŸ› John Wiley and Sons 🌐 English βš– 710 KB

## Abstract Expressions for the probability of a nonadiabatic electron transfer between a donor‐trap and an acceptor‐trap in a polar medium are obtained. The transition probability is expressed in terms of the zeroth‐order electron densities near the traps. The interaction of the electron with the