Femtosecond intermolecular electron (ET) transfer dynamics were studied by time-resolved fluorescence up-conversion technique in contact systems of oxazine dyes in electron-donating solvents. Clearly non-exponential ET time dependence was observed in aniline and explained by the effects of both solv
A quantum mechanical theory of the proton and electron transfer in weakly polar solvents
β Scribed by Alexander M. Kuznetsov
- Publisher
- Elsevier Science
- Year
- 1986
- Weight
- 853 KB
- Volume
- 204
- Category
- Article
- ISSN
- 0022-0728
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
In the present work we have carried out a Monte Carlo simulation of a dissociative electron transfer reaction in a polar solvent. In particular, we have chosen as a very simple model the electrochemical reduction of hydrogen fluoride to give a hydrogen atom and a fluoride anion in a dipolar solvent.
The influence of the classical polar medium fluctuation on the nonradiative transition rate in molecules is considered. Change of the vibrational frequencies under electron excitation is taken into account. In the GaussαMarkov approximation for the fluctuation and the linear model of the vibrational