A very convenient synthetic method is described for the known cyclic aryloxyphosphazenes [N3P3(OC6H4-R)6] (R = Br, CN, CHO, COCH3, COC6H5, and NO,). The method is based on the direct reaction of [N3P3C16] with six equivalents of the para-substituted phenols HOC6H4-R and K&03 in refluxing acetone and
✦ LIBER ✦
On the synthesis of functionalized cyclic and polymeric aryloxyphosphazenes from phenols
✍ Scribed by Gabino A. Carriedo; Lucia Fernández-Catuxo; Francisco J. García Alonso; Paloma Gómez Elipe; Pedro A. González; Gema Sánchez
- Book ID
- 101585358
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 34 KB
- Volume
- 60
- Category
- Article
- ISSN
- 0021-8995
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## Abstract In this report we describe a very convenient synthetic method for the preparation in high yields and purity of cyclic [N~3~P~3~(OCH~2~CF~3~)~6~] and [N~3~P~3~(OC~6~H~4~R)~6~] (R = Br, CN, CHO, COC~6~H~5~, COCH~3~, H, OCH~3~), and polymeric [NP(OC~6~H~4~R)~2~]~__n__~ (R = Br, CHO, COC~6~
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