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On the Synthesis and Crystal Structure of Ba6Cu12Fe13S27: A Discussion

✍ Scribed by Louis J. Cabri; J.T. Szymański


Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
160 KB
Volume
137
Category
Article
ISSN
0022-4596

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The novel thioantimonate(III) [Fe(C 4 H 13 N 3 ) 2 ]Sb 6 S 10 • 0.5 H 2 O was synthesised under mild hydrothermal conditions by allowing elemental Fe, Sb, and S to react in a 50% diethylenetriamine (dien) solution. The compound crystallises in the monoclinic space group C2/c with a = 33.789(3), b =