On the structure of albene
β Scribed by Peter T. Lansbury; Richard M. Boden
- Book ID
- 104238965
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- French
- Weight
- 174 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
β¦ Synopsis
Several years ago, Novotny and coworkers isolated the trisnorsesquiterpene albene (1) from plants of the genera Petasites and Adenostyles.
1 Recently the structure and absolute configuration of 1 were assigned by Herout, Sorm and their cworkers. 2 A major element in their structure proof' was the photo.
chemical degradation of albanone (2) to a decarbonylated olefin, for which they proposed structure 4.
π SIMILAR VOLUMES
Variose is a constituent of an antibiotic, variamycin, and its structure was presented by Lokshin et al. as 2,6-dideoxy-4-01methyl-D-ribo-hexose (l).l Their structure determination depends mostly on analysis of p.m.r. spectrum of methyl varioside (II) which was isolated from a natural product. First
IN Part II2 vs outlined the development of the partial structural formula (I) for the alkaloid arpidoqmmine. The additional ohemiaaf widenoe domcribed iu thim Letter oohfirms thome oonolusious and has a oonsiderabla further beariug on the struoture. While mainly limited to elucidation of the nature