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On the structure of acylaminyl radicals

✍ Scribed by Charles Brown; Alexander J. Lawson

Publisher
Elsevier Science
Year
1975
Tongue
French
Weight
196 KB
Volume
16
Category
Article
ISSN
0040-4039

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✦ Synopsis

The detailed structure of acylaminyl radicals (such as I) has been the subject of much debate.L The ESR measurements of Danen and Cellert', however , resolved much of the controversy surrounding the proposed o and v structures, in that the unpaired electron was deduced to be localised primarily in a nitrogen clear, however, whether the orbital in question la, or is located in the nodal plane as in lb2.

orbital of mainly p-character.

It is not conjugates with the carbonyl n-lobes as in lb 191

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