𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Comments on the structures of phosphoranyl radicals

✍ Scribed by Brian P. Roberts


Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
276 KB
Volume
24
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


The structure and hyperfine splittings o
✍ A. Hudson; R.F. Treweek πŸ“‚ Article πŸ“… 1976 πŸ› Elsevier Science 🌐 English βš– 161 KB

The ab initio UHF method has been employed to calculate equilibrium geometries and isotopic hype&&e coupling ccnstantsfor the radicals PHI, PFa, PH4 and PF4.

31P CIDNP in the reactions of phosphoran
✍ Ya. A. Levin; A. V. Il'yasov; E. I. Goldfarb; E. I. Vorkunova πŸ“‚ Article πŸ“… 1973 πŸ› John Wiley and Sons 🌐 English βš– 419 KB

## Abstract The polarisation of phosphorus nuclei (^31^P CIDNP) during the free radical reactions of triakyl and triaryl phosphites proceeding via intermediate phosphoranyl radicals is discussed.

UHF CNDO/2 study of the phosphoranyl rad
✍ Y.I. Gorlov; V.V. Penkovsky πŸ“‚ Article πŸ“… 1975 πŸ› Elsevier Science 🌐 English βš– 362 KB

The equilibrium geometries and spin density distributions for some phosphoranyl radicals and the radical anion PH30were calculated by the UHF CNDO/2 method. Barriers to permuhtional isomerization in PFQ and PHsOH were estirxted.

Formation and Structure of the Phosphora
✍ Maria Cattani-Lorente; GΓ©rald Bernardinelli; Michel Geoffroy πŸ“‚ Article πŸ“… 1987 πŸ› John Wiley and Sons 🌐 German βš– 442 KB

The crystal structure of 1,2-phenylene phosphorochloridate has been determined. X-Ray irradiation of these crystals, at low temperature, leads to the formation of a radical exhibiting hyperfine structure with P and CI nuclei. The corresponding ESR tensors are obtained, and they show that this radica

Ab initio calculations on Pβ€”C bond cleav
✍ Myong Lim; Christopher J. Cramer πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 156 KB πŸ‘ 1 views

Barrier heights for P-C bond homolysis in P-hydroxy-P-methyl-P,P-dioxophosphoranyl and P,P,Ptrihydroxy-P-methylphosphoranyl were calculated using well correlated levels of electronic structure theory. The best estimate for the difference in barriers between the two indicates that homolysis is more f