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On the stereoisomerization of radicals during aliphatic nucleophilic substitutions

✍ Scribed by Kim Daasbjerg; Torben Lund; Henning Lund


Book ID
108382687
Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
174 KB
Volume
30
Category
Article
ISSN
0040-4039

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It is demonstrated by means of diastereomeric probes that the vieinal nuclcophilic displacement of a diethylphosphatΒ’ group from a I$-(phosphatoxy)alkyl radical may take place by backside or frontside attack depending on stcrie constraints