𝔖 Bobbio Scriptorium
✦   LIBER   ✦

On the status of aliphatic radical anions

✍ Scribed by K.W. Bowers; G.J. Nolfi Jr.; T.H. Lowry; F.D. Greene


Publisher
Elsevier Science
Year
1966
Tongue
French
Weight
152 KB
Volume
7
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis


Some time ago the observation by e.s.r. of ps.rs.maSnetic species derived from cyclopropsne, adamantane, and hexcmctbylenetetrsmine was reported Prcm these laboratories (2). Since that time we have devoted considerable effort to this area with rather conflictini: results which we feel are nevertheless worth summarizing in view of the interes t the work has eqendered (3,4,5);.

Our work has been carried out in two phases (6). In the first phase the fol.lowi.nS observations were made by use of dinethoxyethaneltetrahydrontrrrn


πŸ“œ SIMILAR VOLUMES


ESR Spectra of Radical Anions of Aliphat
✍ Dr. U. Krynitz; Prof. Dr. F. Gerson; Priv.-Doz. Dr. N. Wiberg; Dipl.-Chem. M. Ve πŸ“‚ Article πŸ“… 1969 πŸ› John Wiley and Sons 🌐 English βš– 225 KB πŸ‘ 2 views

I n most cases silicon-nitrogen compounds are readily cleaved by Lewis acids at the Si--N bondL21. Treatment of bisftri-methylsily1)diimine 131 should thus lead to a synthesis of new derivatives of diimine. R--N=N-R:

EPR-studies on the chelation of alkali m
✍ B.J. Herold; M. Celina; R.L.R. Lazana; H.M. Novais πŸ“‚ Article πŸ“… 1977 πŸ› Elsevier Science 🌐 French βš– 399 KB

Abstraet--l,2,4,5-Tetramesitoylbenzene was synthesized and reduced with alkali metals as well as electrolytically. EPR spectra of the resulting radical-ion pairs are reported and discussed. The electron-spin densities obtained from splitting constants are compared to the results of MO calculations.

The remarkable nucleophilicity of supero
✍ Wayne C. Danen; R.Jay Warner πŸ“‚ Article πŸ“… 1977 πŸ› Elsevier Science 🌐 French βš– 250 KB

We wish to report rate constants for the reaction of superoxide anion radical, 02', with various aliphatic bromides in dimethylsulfoxide (DMSO) solution. The results suggest that 02; is one of the most potent nucleophiles yet studied. Superoxide ion is the radical anion derived by adding an electro