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On the stability of CF+·4 ions

✍ Scribed by Martin Schmidt; Rüdiger Seefeldt; Hans Deutsch


Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
450 KB
Volume
93
Category
Article
ISSN
0168-1176

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Weak ion-molecule complexes of F−(CF4)n
✍ Kenzo Hiraoka; Masayuki Nasu; Susumu Fujimaki; Edgar W. Ignacio; Shinichi Yamabe 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 329 KB

Gas-phase thermochemical stabilities and structures of cluster ions F-(CF4) n and CF~-(CF4) ~ have been studied with a high-pressure mass spectrometer and ab initio calculations. The F-... CF a bonding energy is found to be only 6.4 kcal/mol. Its geometry is of an ion-dipole complex along an Sr~2 re