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On the stabilities of transition metal complexes—I Theory of the energies

✍ Scribed by J.Stanley Griffith

Book ID
118903392
Publisher
Elsevier Science
Year
1956
Weight
519 KB
Volume
2
Category
Article
ISSN
0022-1902

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📜 SIMILAR VOLUMES

On the theory of ligand substitution in
On the theory of ligand substitution in transition metal complexes
✍ K.G. Breitschwerdt 📂 Article 📅 1967 🏛 Elsevier Science 🌐 English ⚖ 207 KB

Expressions are given for the calculation of activation energies for ligand substitution in transition metal complexes. A comparison between calculated and experimental activation energies for the substitution of water molecules shows reasonably good agreement.

Substituent Effects on the Bond-Dissocia
Substituent Effects on the Bond-Dissociation Energies of Cationic Arene−Transition-Metal Complexes
✍ Katrin Schroeter; Ralf Wesendrup; Helmut Schwarz 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 508 KB

The bond-dissociation energies (BDEs) of more than twenty areneϪM + complexes (M = Cr, Fe, Co) have been studied by mass spectrometry, using the kinetic method. With minor exceptions, the same relative order of BDEs is found for the three metals and the series of substituted arenes: electrondonating