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On the spectroscopic evidence for geometry in (SiH3)3P and (SiH3)3As

✍ Scribed by D.C. McKean

Book ID
113371990
Publisher
Elsevier Science
Year
1968
Tongue
English
Weight
167 KB
Volume
24
Category
Article
ISSN
1386-1425

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Theoretical study and rate constants calculation for the reactions of SiH3 radical with SiH3CH3 and SiH2(CH3)2
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## Abstract The multiple‐channel reactions SiH~3~ + SiH~3~CH~3~ β†’ products and SiH~3~ + SiH~2~(CH~3~)~2~ β†’ products are investigated by direct dynamics method. The minimum energy path (MEP) is calculated at the MP2/6‐31+G(d,p) level, and energetic information is further refined by the MC‐QCISD meth