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On the Shape of a Diels–Alder Ladder Polymer

✍ Scribed by Dr. Britta L. Schürmann; Dr. habil. Volker Enkelmann; Dipl.-Chem. Matthias Löffler; Prof. Dr. Arnulf-Dieter Schlüter

Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
316 KB
Volume
32
Category
Article
ISSN
0044-8249

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The activation and reaction volumes (∆V /∆V) were showing negative volumes of activation (∆V Ͻ 0) whereas the others are slightly retarded (∆V Ͼ 0). From the analysis determined for the retro Diels-Alder reactions of the parent dihydrobarrelene 1a, its 2-cyano derivative 1b, the exo and of the volum