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On the role of solvent in complexation equilibria. I. The acid-base chemistry of some α,ω-diaminocarboxylic acids in water-dioxane mixed solvents

✍ Scribed by Robert Griffith; Lakshmikumar Pillai; Mark S. Greenberg


Publisher
Springer US
Year
1979
Tongue
English
Weight
612 KB
Volume
8
Category
Article
ISSN
0095-9782

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The kinetics of base hydrolysis of some (aminomonocarboxylato)(tetraethylenepentamine)cobalt(III) complexes, [(tetren have been investigated in methanol-water media (0-80 vol % MeOH) at 15.0 Յ tЊC Յ 40.0 (0.02 mol dm Ϫ3 NaOH). The second-order rate constant at zero ionic strength, k 2 Њ, increases