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On the Role of Polarizability in Chemical-Biological Interactions

✍ Scribed by Hansch, C.; Steinmetz, W.E.; Leo, A.J.; Mekapati, S.B.; Kurup, A.; Hoekman, D.

Book ID
121000916
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
43 KB
Volume
43
Category
Article
ISSN
0095-2338

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In the present work, a theoretical analysis was carried out on the effect of the proximity of a polar bond to a polarizable bond on the magnetic shielding constants of the nuclei belonging to the polarizable bond. In particular, the case of 13 C magnetic shielding constants in a vinylic C C bond is