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Long-range effects of molecular interactions on the polarizability of atoms

✍ Scribed by A.D. Buckingham; K.L. Clarke


Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
393 KB
Volume
57
Category
Article
ISSN
0009-2614

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πŸ“œ SIMILAR VOLUMES


The polarizability of a pair of hydrogen
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The coeft?cIen ts of i7+ and R-O III the long-range expansion of the parallel and pet-pendlcular components of tie Af P olarlzablhty of a Parr of hydrogen atoms at a separation R have been calcula?ed The results are A [F) = 2.558 59. = 1268 25,A)(l")= 90639 5 XI~IA~)= 22010 3 XI The valuesof~~) and

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The effect of the weak long-range interaction on the shielding constant is considered for a pair of interacting atoms. The asymptotic long-range effects are proportional to R-" (where R is the interatomic distance). For the anisotropy of the shielding tensor n = 3, for the trace n = 6 for two neutra

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The long range part of the electric dipole momentp(R 12R13R& of three inte:acting atoms is calculated as a power series in R,T1. The terms of longest range are of the types R ,\*