On the role of polarity of adsorbate and solvent molecules in adsorption of organic substances on electrodes
β Scribed by B.B. Damaskin; A.N. Frumkin
- Publisher
- Elsevier Science
- Year
- 1972
- Weight
- 543 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0022-0728
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π SIMILAR VOLUMES
The adsorption ofdimethylsulphoxide and reactions ofadsorbed molecules at platinized platinum electrode were studied by potentiodynamic and radiometric techniques. The adsorption of dimethylsulphoxide is described by femkin type isotherm. The adsorbed dimethylsulphoxide is reduced in two steps to di
It is shown that if the shape of the adsorption isotherm does not depend on the electrode potential q and the double layer capacitance C decreases to a certain limiting value with increasing concentration of the organic substance, the energy of adsorption is a quadratic function of p. In this case,