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On the Role of Intermolecular Interactions on Structural and Spin-Crossover Properties of 2D Coordination Networks [Fe(bbtr)3]A2 (bbtr=1,4-bis(1,2,3-triazol-1-yl)butane; A=ClO4−, BF4−)

✍ Scribed by Prof. Dr. Joachim Kusz; Dr. Robert Bronisz; Maciej Zubko; Gabriela Bednarek


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
608 KB
Volume
17
Category
Article
ISSN
0947-6539

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Nanoparticles of [Fe(NH2-trz)3]Br2⋅3 H2O
✍ Thibaut Forestier; Abdellah Kaiba; Stanislav Pechev; Dominique Denux; Philippe G 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 854 KB

## Abstract By changing the surfactant/water ratio, nanoparticles of the iron(II) spin crossover material, [Fe(NH~2~‐trz)~3~]Br~2~⋅3 H~2~O (with NH~2~‐trz=4‐amino‐1,2,4‐triazole), have been synthesised from 1 μm down to 30 nm (see figure). Magnetic and reflectivity experiments indicate that the cri