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On the Relationship Between Entropy and Enthalpy of Grain Boundary Segregation

✍ Scribed by Pavel Lejček; Siegfried Hofmann


Book ID
110334009
Publisher
Springer
Year
2001
Tongue
English
Weight
101 KB
Volume
9
Category
Article
ISSN
0927-7056

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Role of entropy in anistropy of grain bo
✍ Lej?ek, Pavel 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 240 KB

From the viewpoint of existence of linear dependence between entropy and enthalpy of grain boundary segregation, the meaning of the entropy term is discussed. It is suggested that negative values of segregation entropy for silicon segregation at individual grain boundaries in a-iron reÑect an "order