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On the Rearrangement of an Azaspiroindolenine to a Precursor to Phalarine: Mechanistic Insights

✍ Scribed by Chaomin Li; Collin Chan; Annekatrin C. Heimann; Samuel J. Danishefsky

Book ID
101535422
Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
365 KB
Volume
119
Category
Article
ISSN
0044-8249

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✍ Mrinmoy Nag; Peter P. Gaspar 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 340 KB 👁 2 views

## Abstract Roark and Peddle first observed that, when not trapped, Me~2~SiSiMe~2~ underwent a series of rearrangements to give two major isomeric products: 1,1‐dimethyl‐1,3‐disilacyclobutane and 1,3‐dimethyl‐1,3‐disilacyclobutane. The widely accepted mechanism for this rearrangement was proposed