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Mechanistic insights into the rearrangement of azetidine N-oxides to isoxazolidines

✍ Scribed by Laurence Menguy; Bruno Drouillat; Jérome Marrot; François Couty

Book ID
116909683
Publisher
Elsevier Science
Year
2012
Tongue
French
Weight
625 KB
Volume
53
Category
Article
ISSN
0040-4039

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## Abstract __During the biosynthesis of certain tropane alkaloids, littorine (**1**) is rearranged to hyoscyamine (**3**). Recent evidence indicates that this isomerisation is a two‐step process in which the first step is an oxidation/rearrangement to give hyoscyamine aldehyde (**2**). This step i