It has been demonstrated by means of spectroscopic studies involving cyclizable alkyl halides that lithium dimethylcuprate can react with organic halides by a single electron transfer pathway. The reaction of lithium diorganocuprates (LiCuR2) with alkyl halides is of major synthetic imp0rtance.l
On the reaction of lithium diisopropylamide with .pi.-deficient heteroaromatics. A single electron transfer mechanism
โ Scribed by Newkome, George R.; Hager, David C.
- Book ID
- 127281720
- Publisher
- American Chemical Society
- Year
- 1982
- Tongue
- English
- Weight
- 398 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The reduction of benzophenone by lithium alkoxides gives rise to benzophenone ketyl which disappears in a first-order fashion and whose first-order rate constant is approximately equal to the pseudo-first-order rate constant for the formation of the product, benzhydrol.
Evidence for a radical process in the reaction of the lithium enolate of propiophenone with a primary alkyl iodide was obtained by the observation of cyclization of an appropriate radical probe, by the trapping of the radical intermediate and by the comparison of the relative rates of reactions of t