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On the product vibrational distribution of exoergic reactions: the B + OH system

✍ Scribed by A. Aguilar; M. Albertì; X. Gimenez; X. Grande; A. Laganà

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
384 KB
Volume
233
Category
Article
ISSN
0009-2614

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✦ Synopsis

The dependence on the collision energy of the product vibrational distribution of exoergic reactions has been investigated by carrying out model and coupled channel calculations for the B + OH ~ BO + H process. The location and number of peaks of the three-dimensional results differ from those obtained from collinear and model calculations and agree better with available experimental information. A rationale for this is discussed in terms of the selective product vibrational excitation associated with different orbital angular momentum values.

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Anomalously high vibrational excitation
Anomalously high vibrational excitation in the product OH from the reaction of O(1D) with tetramethylsilane
✍ Seiichiro Koda; Shinsuke Suga; Congxiang Chen 📂 Article 📅 1990 🏛 Elsevier Science 🌐 English ⚖ 448 KB

The vibrational excitation of the product OH from the reaction of 0( 'D) with tetramethylsilane has been found to be anomalously high compared to that from the reaction with neopentane, which suggests that the energy migration mechanism in the intermediate of the above reactions is considerably depe