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Anomalously high vibrational excitation in the product OH from the reaction of O(1D) with tetramethylsilane

✍ Scribed by Seiichiro Koda; Shinsuke Suga; Congxiang Chen

Publisher: Elsevier Science
Year: 1990
Tongue: English
Weight: 448 KB
Volume: 173
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(90)80083-p

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✦ Synopsis

The vibrational excitation of the product OH from the reaction of 0( 'D) with tetramethylsilane has been found to be anomalously high compared to that from the reaction with neopentane, which suggests that the energy migration mechanism in the intermediate of the above reactions is considerably dependent on the nature of the central atom. whether it is silicon or carbon.

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