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CO vibrational population distributions in the reactions of COS with O(3PJ) and O(1D2) atoms

✍ Scribed by R.G. Shortridge; M.C. Lin

Publisher: Elsevier Science
Year: 1975
Tongue: English
Weight: 566 KB
Volume: 35
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(75)85606-5

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✦ Synopsis

The populations of the nascent CO formed in the reactions oi COS with 0(3P~) and O(" Dz) atoms: O? P) + cos s co? + so, O(' D) c COS 4 COi + SO have been determined by a CO laser resonant absorption method. The fraction of the total available energy channelled into CO as vibration ~1s calculated to be 11% in reaction (3) and only about 4% in (4). A simUar experiment for the O(' D) + CO? reaction showed no appteciabie CO production. ' NRLjNRC Postdoctoral Research Associate (1973-present). * l&e values were calculated on ihe basis of AH: = -21 kc&f mote, instead of-fi kciljrriole, 3s discussed in ref. ISI.

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