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On the problem of regioselectivity in the 1,3-dipolar cycloaddition reaction of munchnones and sydnones with acetylenic dipolarophiles

✍ Scribed by Padwa, Albert; Burgess, Edward M.; Gingrich, Henry L.; Roush, David M.

Book ID
118002851
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
842 KB
Volume
47
Category
Article
ISSN
0022-3263

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Theoretical study of the reaction mechan
Theoretical study of the reaction mechanism and solvent effect on the regioselectivity of 1,3-dipolar cycloaddition reaction between azide and acetylene derivatives
✍ Xi-Bo Li; Qin-Hua Song πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 109 KB πŸ‘ 2 views

## Abstract The reaction mechanism and solvent‐dependant regioselectivity of 1,3‐dipolar cycloaddition reactions between azide and acetylene derivatives have been studied using computational methods. The two possible reaction transition states were located. Geometry and NBO analysis found that the