## Abstract Lifetime data have been obtained for the decay of SO~2~(^3^__B__~1~ 0,0,0) at 25Β°C over the pressure range of 1β762 torr. The ^3^__B__~1~ state was populated by direct absorption to eliminate any possible complications in interpretation due to the participation of excitedβsinglet manifo
On the pressure saturation effect of the quenching of SO2(3B1) molecules
β Scribed by Fu Su; Fred B. Wampler; Jan W. Bottenheim; David L. Thorsell; Jack G. Calvert; Edward K. Damon
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 430 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0009-2614
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A competitive technique employing the S 0 2 ( 3 B , ) photosensitized isomerization of cis-C2F2H2 to trans-C2FzH2 in the presence of selected fluorinated olefins has been used at 3712 d and 22Β°C to determine the quenching rate constants of the reaction S02(aB~) + M 3 removal. With tJs0, = 23.4 torr
Ihe surface of the lowest excited smgkt state in meth;lne IS analyzed usmg a basis yet composed of 4-3 IC; augmented by a set of one s and three p Rydbergs. The State (IT2 in Td syrnnrctry. 1 Li, In C 2v! is fmnd to bc dissociatlvc to I B I Cllz and ground state &. Vcrtirally a llydbcrg state, 1B1 r