On the preparation of amine N-oxides by using dioxiranes
✍ Scribed by Marta Ferrer; Francisco Sánchez-Baeza; Angel Messeguer
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- French
- Weight
- 687 KB
- Volume
- 53
- Category
- Article
- ISSN
- 0040-4020
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The reactivity of dimethyldioxirane and methyl(trifluoro-luminescence and by chemical trapping with 9,10-dimethylanthracene. The nucleophilicity of the N-oxide determines methyl)dioxirane towards the amine N-oxides 1a-13a and ammonium derivatives 13b-d has been investigated. In the the efficacy of t
An efficient approach to the synthesis of N-hydroxyamino acids in high enantiomeric excess is described; this involves the high-yielding selective N-hydroxylation of N-Boc protected primary amino acid esters with methyl(trifluoromethyl)dioxirane under mild conditions.