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On the Possibility of Using UV Spectroscopy as a Measure of the Low-Barrier Hydrogen Bond

✍ Scribed by Lloyd A. Butler; Jeffrey E. Miller; Christopher J. Halkides; Michael Messina

Book ID
111612377
Publisher
Springer
Year
2003
Tongue
English
Weight
98 KB
Volume
14
Category
Article
ISSN
1040-0400

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There are large differences between the acidity of the enol of the acyclic diketone, 2,4-pentanedione and those of two cyclic diketones, 1,3-cyclopentanedione and 1,3-cyclohexanedione. Computational studies have demonstrated that these differences are largely due to the strength of the internal low-