The high resofution photoelectron spectrum of CS has been obtained. Ionization potrntkds are found nt 11.34 (Xk), 17.78 (A\*lB, 15.83 (Bzc) and 18.03 (C'X) eV, and a spin-orbit bT;plitting of 278 cm-' is observed on the second band.
On the photoelectron spectrum of CS2
โ Scribed by M.-J. Hubin-Franskin; J. Delwiche; P. Natalis; G. Caprace; D. Roy
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 720 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0368-2048
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๐ SIMILAR VOLUMES
The high-resolution zero kinetic energy photoelectron spectrum of CS2 is presented. Accurate values for the ionization potential and the spin-orbit splitting of the R+ '4 are obtained. Observation of the symmetry-forbidden excitations of the p2 bending vibration yields accurate frequencies for this
The ionization potentials and the vibrational structure in the photoelectron spectrum of the CS molecule are calculated using a Green's function approach. The inclusion of many-body corrections to Koopmans' theorem is necessary in order to obtain the correct ordering of the first two ionization pote