On the photochemical behaviour of ethyl acetoacetate in water
✍ Scribed by Peter Markov; Ivan Petkov; Christian Roumian
- Publisher
- Springer Vienna
- Year
- 1983
- Tongue
- English
- Weight
- 160 KB
- Volume
- 114
- Category
- Article
- ISSN
- 0026-9247
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📜 SIMILAR VOLUMES
Recent insights (1) in the remarkable solvent properties of dimethyl eulfoxida (DMSO), and our own interest in the chemistry of isopropcnyl ethers (2) led u8 to consider the poraibility of direot 0-alkylation of ethyl aoetoaoetate in that solvent. The connection i# that Kornblum'rr work (3) suggests
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## Abstract Condensation of 3‐nitro‐1,2‐phenylenediamine with ethyl acetoacetate in boiling xylene gave two isomeric 2,3‐dihydro‐4‐methyl‐9‐nitro‐ and 2,5‐dihydro‐4‐methyl‐6‐nitro‐1__H__‐1,5‐benzodiazepin‐2‐ones, the 9‐nitro derivative thermal rearrangement product __N__‐isopropenyl‐4‐nitrobenzimid