A new computational method to account for the effect of anharmonicities on non-radhtive decay ratesofkge molecules in the statisti~l limit is given by using expansions of the generating functions which have been used successfully 'ffl multiphor;on processes. This method is free from the ambiguity wh
On the perturbation description of radiationless transitions
โ Scribed by G. Orlandi; W. Siebrand
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 439 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
A nonempirical
criterion is derived for determining the representation apprcpriate to a first-order perturbation description of radiationless transitions.
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