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On the palladium-catalyzed alkylation of silyl-substituted allyl acetates with enolates

โœ Scribed by Trost, Barry M.; Self, Christopher R.


Book ID
126786334
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
771 KB
Volume
49
Category
Article
ISSN
0022-3263

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The fwst asymmetric cyclopropanation of ketene silyl acetal with allylic acetate was achieved. New chiral oxazolidinylpyrazole ligands and their TlLallylpalladium complexes were synthesized. Reaction of cinnamyl acetate with ketene silyl acetal of ethyl isobutylate in the presence of a palladium com