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Palladium-catalyzed silylation of allylic acetates with hexamethyldisilane or (trimethylsilyl)tributylstannane

โœ Scribed by Tsuji, Yasushi; Kajita, Satoshi; Isobe, Shinya; Funato, Masahiro


Book ID
125899742
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
266 KB
Volume
58
Category
Article
ISSN
0022-3263

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Asymmetric cyclopropanation of ketene si
โœ Akiharu Satake; Hitomi Kadohama; Hiroyuki Koshino; Tadashi Nakata ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 239 KB

The fwst asymmetric cyclopropanation of ketene silyl acetal with allylic acetate was achieved. New chiral oxazolidinylpyrazole ligands and their TlLallylpalladium complexes were synthesized. Reaction of cinnamyl acetate with ketene silyl acetal of ethyl isobutylate in the presence of a palladium com