𝔖 Bobbio Scriptorium
✦   LIBER   ✦

On the Pace–Datyner theory of diffusion of small molecules through polymers

✍ Scribed by A. Kloczkowski; J. E. Mark

Publisher
John Wiley and Sons
Year
1989
Tongue
English
Weight
413 KB
Volume
27
Category
Article
ISSN
0887-6266

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Self-diffusion of small molecules into r
Self-diffusion of small molecules into rubbery polymers: A lattice free-volume theory
✍ L. I. Costa; G. Storti 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 391 KB

## Abstract In the framework of the free‐volume (FV) theory, a new equation was derived for the evaluation of self‐diffusion coefficients of small molecules in polymers above the mixture glass transition temperature. The derivation of the equation turned out to be straightforward once the equivalen

The influence of penetrant concentration
The influence of penetrant concentration on the diffusion and permeation of small molecules in polymers above tg
✍ P. Meares 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 582 KB

The diffusion of fairly small organic molecules in polymers above their glass transitions is normally governed by Fick's law but with diffusion coetficients that are strongly, almost exponentially, increasing functions of penetrant concentration. Attempts to develop a comprehensive and quantitative

Effect of chain length on rates of diffu
Effect of chain length on rates of diffusion-limited small molecule-polymer and polymer-polymer reactions: Phosphorescence quenching studies
✍ Marc B. Wisnudel; John M. Torkelson 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 887 KB

Model interactions have been studied by phosphorescence quenching to obtain a better understanding of the chain length dependence of interpolymeric chain end-chain end reactions such as those involved in the termination step of free radical polymerization. For small molecule-polymer interactions in